The actress teamed up with the singer after winning rave reviews for her knockout cover of the song on Glee.
She's made quite an impression on Cee Lo he told People she's a "natural".
"We already went into the studio together to record a special rendition of 'Forget You'," he said.
"I started off the new year [in] a very special way and that's recording with Miss Gwyneth."
Gwyneth is hosting the January 15 episode of Saturday Night Live, with Cee Lo Green performing on the same show.
Watch Cee Lo Green's original 'Forget You' music video: